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(Trimethylsilyl)acetylene, 98%, Thermo Scientific Chemicals

Product Code. 11425273
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Quantity:
5 g
25 g
100 g
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(Trimethylsilyl)acetylene is used in the preparation of trimethylsilanyl-propiolic acid ethyl ester by reacting with carbonochloridic acid ethyl ester as well as in the synthesis of iodoalkenes by radical addition of perfluoroalkyl iodides. It is used as a nucleophile in Friedel-Crafts type acylations and alkylations reactions, as a ligand in organometallic chemistry and an useful reagent in cycloaddition reactions. It acts as a precursor to lithium trimethylsilylacetylide It finds application in the synthesis of (±)-estrone.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(Trimethylsilyl)acetylene is used in the preparation of trimethylsilanyl-propiolic acid ethyl ester by reacting with carbonochloridic acid ethyl ester as well as in the synthesis of iodoalkenes by radical addition of perfluoroalkyl iodides. It is used as a nucleophile in Friedel-Crafts type acylations and alkylations reactions, as a ligand in organometallic chemistry and an useful reagent in cycloaddition reactions. It acts as a precursor to lithium trimethylsilylacetylide It finds application in the synthesis of (±)-estrone.

Solubility
Miscible with organic solvents.

Notes
Store in a cool place. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 1066-54-2
Molecular Formula C5H10Si
Molecular Weight (g/mol) 98.22
MDL Number MFCD00008569
InChI Key CWMFRHBXRUITQE-UHFFFAOYSA-N
Synonym trimethylsilylacetylene, trimethylsilyl acetylene, silane, ethynyltrimethyl, ethynyl-trimethyl-silane, ethynyl trimethyl silane, tms acetylene, ethynyltrimethyl silane, trimethylsilyl-acetylene, tmsacetylene
PubChem CID 66111
IUPAC Name ethynyl(trimethyl)silane
SMILES C[Si](C)(C)C#C

Specifications

Boiling Point 52°C to 53°C
Quantity 100 g
Linear Formula HC≡CSi(CH3)3
UN Number UN1993
Beilstein 906752
Flash Point <−34°C (−29°F)
Solubility Information Miscible with organic solvents.
Formula Weight 98.22
Percent Purity 98%
Refractive Index 1.39
Density 0.71
Chemical Name or Material (Trimethylsilyl)acetylene
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Product Identifier
  • (Trimethylsilyl)acetylene
Signal Word
  • Danger
Hazard Category
  • Flammable liquid Category 2
Hazard Statement
  • H225-Highly flammable liquid and vapour.
Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P240-Ground/bond container and receiving equipment.
Supplemental information
  • MIXTURE LIST-Contains : (Trimethylsilyl)acet

RUO – Research Use Only

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