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Tin(II) chloride, anhydrous, 98%, Thermo Scientific Chemicals

39.09 € - 403.01 €

Chemical Identifiers

CAS 7772-99-8
Molecular Formula Cl2Sn
Molecular Weight (g/mol) 189.61
MDL Number MFCD00011241
InChI Key AXZWODMDQAVCJE-UHFFFAOYSA-L
Synonym Stannous chloride, anhydrous
PubChem CID 24479
ChEBI CHEBI:78067
IUPAC Name dichlorotin
SMILES [Cl-].[Cl-].[Sn++]
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Thermo Scientific Alfa Aesar
A16202.22
100 g
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Thermo Scientific Alfa Aesar
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Description

Description

Tin(II) chloride is widely used as a reducing agent in organic synthesis, for example conversion of quinones into hydroquinones, nitroaromatics into aromatic amines, and in Stephen reduction. It can be used to reduce certain metal salts into metals, tin plating, analytical testing of mercury ions, formation of silver mirrors and metal-metal bonds. It is also used for tin-plating, as a mordant in textile dyeing and as a catalyst in the production of polylactic acid. Further it is used as a food additive, wherein it serves as an anti-oxidant and a color retention agent. It can be used in the condensation of aryl aldehydes with cyclohexan-1,3-diones to synthesize xanthenes. It catalyzes direct conversion of aldehydes into beta-keto esters.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Tin(II) chloride is widely used as a reducing agent in organic synthesis, for example conversion of quinones into hydroquinones, nitroaromatics into aromatic amines, and in Stephen reduction. It can be used to reduce certain metal salts into metals, tin plating, analytical testing of mercury ions, formation of silver mirrors and metal-metal bonds. It is also used for tin-plating, as a mordant in textile dyeing and as a catalyst in the production of polylactic acid. Further it is used as a food additive, wherein it serves as an anti-oxidant and a color retention agent. It can be used in the condensation of aryl aldehydes with cyclohexan-1,3-diones to synthesize xanthenes. It catalyzes direct conversion of aldehydes into beta-keto esters.

Solubility
Soluble in ethanol, acetone, ether and tetrahydrofuran. Insoluble in xylene.

Notes
Tin(II) chloride is very freely soluble in cold water. If the volume of water increases or at hot condition it hydrolyses to form an insoluble hydroxide derivative.
Specifications

Chemical Identifiers

7772-99-8
189.61
AXZWODMDQAVCJE-UHFFFAOYSA-L
24479
dichlorotin
Cl2Sn
MFCD00011241
Stannous chloride, anhydrous
CHEBI:78067
[Cl-].[Cl-].[Sn++]

Specifications

652°C
7772-99-8
MFCD00011241
14,8783
Soluble in ethanol,acetone,ether and tetrahydrofuran. Insoluble in xylene.
[Cl-].[Cl-].[Sn++]
189.61
CHEBI:78067
98%
3.95
247°C
Cl2Sn
UN3260
Stannous chloride, anhydrous
AXZWODMDQAVCJE-UHFFFAOYSA-L
dichlorotin
24479
189.62
Air sensitive; Hygroscopic
Tin(II) chloride, anhydrous
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Safety and Handling

Safety and Handling

GHS H Statement
H314-H318-H302-H317
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.
May cause an allergic skin reaction.

P234-P260-P264b-P270-P271-P272-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P390-P501c

H290-H302+H332-H314-H317-H335-H373

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Recommended Storage : Ambient temperatures

Product Identifier
  • Tin(II) chloride, anhydrous

Signal Word
  • Danger

Hazard Category
  • Acute toxicity Category 4
  • LONG-TERM AQUATIC HAZARD Chronic 3
  • Serious eye damage/eye irritation Category 1
  • Substances and mixtures corrosive to metals Category 1
  • Skin corrosion/irritation Category 1 B
  • Skin sensitiser Category 1
  • Specific target organ toxicity after repeated exposure Category 2
  • Specific target organ toxicity Category 3

Hazard Statement
  • H290-May be corrosive to metals.
  • H302-Harmful if swallowed.
  • H314-Causes severe skin burns and eye damage.
  • H317-May cause an allergic skin reaction.
  • H318-Causes serious eye damage.
  • H332-Harmful if inhaled.
  • H335-May cause respiratory irritation.
  • H373-May cause damage to organs.
  • H412-Harmful to aquatic life with long lasting effects.

Precautionary Statement
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.

Supplemental information
  • MIXTURE LIST-Contains : Stannous chloride

SDS
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Product Certifications

RUO – Research Use Only

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