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Terephthaloyl chloride, 99%, Thermo Scientific Chemicals

Product Code. 11443554
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Quantity:
250 g
1000 g
This item is not returnable. View return policy
This item is not returnable. View return policy

Terephthaloyl chloride acts as a monomer with p-phenylenediamine used in the preparation of polymer viz. poly paraphenylene terephthalamide. It is an active component in performance polymers and aramid fibers, which gives flame resistance, chemical resistance, temperature stability, light weight, and very high strength. It is also used as an effective water scavenger, utilized to stabilize isocyanates and urethane prepolymers. Further, it is used in the preparation of liquid crystalline thermosets by thermal cyclotrimerization of dicyanate compounds of ring substituted bis(4-hydroxyphenyl) terepthalates. In addition to this, it is involved in the condensation reaction with difunctional alfa, μ-diaminopolystyrene to get chain-extended polystyrene containing amide bonds along the polymer backbone.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Terephthaloyl chloride acts as a monomer with p-phenylenediamine used in the preparation of polymer viz. poly paraphenylene terephthalamide. It is an active component in performance polymers and aramid fibers, which gives flame resistance, chemical resistance, temperature stability, light weight, and very high strength. It is also used as an effective water scavenger, utilized to stabilize isocyanates and urethane prepolymers. Further, it is used in the preparation of liquid crystalline thermosets by thermal cyclotrimerization of dicyanate compounds of ring substituted bis(4-hydroxyphenyl) terepthalates. In addition to this, it is involved in the condensation reaction with difunctional alfa, µ-diaminopolystyrene to get chain-extended polystyrene containing amide bonds along the polymer backbone.

Solubility
Soluble in ethanol, ether and other common organic solvents.

Notes
Incompatible with alcohols, oxidizing agents, water and strong bases.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 100-20-9
Molecular Formula C8H4Cl2O2
Molecular Weight (g/mol) 203.02
MDL Number MFCD00000693
InChI Key LXEJRKJRKIFVNY-UHFFFAOYSA-N
Synonym terephthaloyl chloride, terephthaloyl dichloride, 1,4-benzenedicarbonyl dichloride, terephthalic acid dichloride, terephthalic dichloride, p-phthaloyl chloride, terephthalic acid chloride, p-phthalyl dichloride, p-phthaloyl dichloride, terephthalyl dichloride
PubChem CID 7488
IUPAC Name benzene-1,4-dicarbonyl chloride
SMILES ClC(=O)C1=CC=C(C=C1)C(Cl)=O

Specifications

Melting Point 79°C to 83°C
Boiling Point 265°C
Flash Point 180°C (356°F)
Quantity 1000 g
UN Number UN2928
Beilstein 607796
Sensitivity Moisture sensitive
Solubility Information Soluble in ethanol,ether and other common organic solvents.
Formula Weight 203.02
Percent Purity 99%
Chemical Name or Material Terephthaloyl chloride
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Product Identifier
  • Terephthaloyl chloride
Signal Word
  • Danger
Hazard Category
  • Acute toxicity Category 3
  • Serious eye damage/eye irritation Category 1
  • Skin corrosion/irritation Category 1 A
Hazard Statement
  • H314-Causes severe skin burns and eye damage.
  • H318-Causes serious eye damage.
  • H331-Toxic if inhaled.
Precautionary Statement
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.
Supplemental information
  • MIXTURE LIST-Contains : 1,4-Benzenedicarbonyl dichloride

RUO – Research Use Only

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