missing translation for 'onlineSavingsMsg'
Learn More
  1. Home
  2. Products
  3. Chemicals
  4. Salts and Inorganics
  5. Inorganic Salts
  6. Metalloid Salts
  7. Sodium bis(trimethylsilyl)amide, 2M soln. in THF, Thermo Scientific Chemicals

Sodium bis(trimethylsilyl)amide, 2M soln. in THF, Thermo Scientific Chemicals

Product Code. 11358066
Click to view available options
Quantity:
100 mL
500 mL

Description

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Sodium bis(trimethylsilyl)amide is a strong base used in organic synthesis for deprotonation reactions and base catalyzed reaction. It is also used to enhance the polymerization of pheneylacetylene in conjunction with rhodium(I) catalysis. It is involved in the generation of enolates, Wittig reagents and carbenes.

Solubility
Miscible with benzene and toluene.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents, strong oxidizing agents and oxygen. Dry residue is explosive.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 1070-89-9
Molecular Formula C6H18NNaSi2
Molecular Weight (g/mol) 183.377
MDL Number MFCD00009835
InChI Key WRIKHQLVHPKCJU-UHFFFAOYSA-N
Synonym sodium bis trimethylsilyl amide, n-sodiohexamethyldisilazane, sodium hexamethyldisilazide, nahmds, sodiobis trimethylsilyl amine, sodium bis trimethylsilyl azanide, n-sodium hexamethyldisilazane, sodium-bis trimethylsilyl amide, hexamethyldisilazane sodium salt
PubChem CID 2724254
IUPAC Name sodium;bis(trimethylsilyl)azanide
SMILES C[Si](C)(C)[N-][Si](C)(C)C.[Na+]

Specifications

Quantity 100 mL
UN Number UN2924
Beilstein 3629917
Flash Point −17°C (1°F)
Solubility Information Miscible with benzene and toluene.
Formula Weight 183.38
Concentration or Composition (by Analyte or Components) 2M soln. in THF
Sensitivity Moisture sensitive; May form a precipitate
Density 0.92
Chemical Name or Material Sodium bis(trimethylsilyl)amide

Safety and Handling

compliance-icons compliance-icons compliance-icons compliance-icons
Product Identifier
  • Sodium bis(trimethylsilyl)amide, 2M solution in THF
 Signal Word
  • Danger
 Hazard Category
  • Acute toxicity Category 4
  • LONG-TERM AQUATIC HAZARD Chronic 3
  • Carcinogenicity Category 2
  • Serious eye damage/eye irritation Category 1
  • Flammable liquid Category 2
  • Germ cell mutagenicity Category 2
  • Skin corrosion/irritation Category 1 B
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H225-Highly flammable liquid and vapour.
  • H302-Harmful if swallowed.
  • H314-Causes severe skin burns and eye damage.
  • H318-Causes serious eye damage.
  • H335-May cause respiratory irritation.
  • H336-May cause drowsiness or dizziness.
  • H341-Suspected of causing genetic defects.
  • H351-Suspected of causing cancer.
  • H412-Harmful to aquatic life with long lasting effects.
  • EUH014-Reacts violently with water.
  • EUH019-May form explosive peroxides.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.
 Supplemental information
  • MIXTURE LIST-Contains : Tetrahydrofuran, Sodium bis(trimethylsilyl)amide

RUO – Research Use Only

Product Content Correction

Your input is important to us. Please complete this form to provide feedback related to the content on this product.

Product Title

By clicking Submit, you acknowledge that you may be contacted by Fisher Scientific in regards to the feedback you have provided in this form. We will not share your information for any other purposes. All contact information provided shall also be maintained in accordance with our Privacy Policy.

Thank You! Your feedback has been submitted. Fisher Scientific is always working to improve our content for you. We appreciate your feedback.