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Methyltrioxorhenium(VII), 98%, Thermo Scientific Chemicals
45.50 € - 148.00 €
Chemical Identifiers
CAS | 70197-13-6 |
---|---|
Molecular Formula | CH3O3Re- |
Molecular Weight (g/mol) | 249.239 |
MDL Number | MFCD00192332 |
InChI Key | VZSXFJPZOCRDPW-UHFFFAOYSA-N |
Synonym | methyltrioxorhenium vii, methyltrioxorhenium, methylrhenium trioxide, unii-883d8rdd5q, methylrhenium vii trioxide, mto, methyltrioxorhenium mi, t-4-methyltrioxorhenium, methylrhenium trioxide vii |
PubChem CID | 2734010 |
IUPAC Name | carbanide;trioxorhenium |
SMILES | [CH3-].O=[Re](=O)=O |
Description
Methyltrioxorhenium(VII) is used as a catalyst for various transformations such as olefin metathesis. It is associated with hydrogen peroxide and used as an oxidizing agent. It is used to prepare acid or ester from the corresponding terminalalkynes. It is a catalytic oxidant used with urea hydrogen peroxide to prepare nitrones. It reacts with 2-methylnaphthalene to get 2-methyl-1,4-naphthoquinone (Vitamin K3). Further, it catalyzes the reaction with aldehydes and diazoketones to get an alkene. In addition to this, it is used as an effective antioxidant under various conditions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsMethyltrioxorhenium(VII) is used as a catalyst for various transformations such as olefin metathesis. It is associated with hydrogen peroxide and used as an oxidizing agent. It is used to prepare acid or ester from the corresponding terminalalkynes. It is a catalytic oxidant used with urea hydrogen peroxide to prepare nitrones. It reacts with 2-methylnaphthalene to get 2-methyl-1,4-naphthoquinone (Vitamin K3). Further, it catalyzes the reaction with aldehydes and diazoketones to get an alkene. In addition to this, it is used as an effective antioxidant under various conditions.
Solubility
Soluble in water.
Notes
Incompatible with strong oxidizing agents.
Chemical Identifiers
70197-13-6 | |
249.239 | |
VZSXFJPZOCRDPW-UHFFFAOYSA-N | |
2734010 | |
[CH3-].O=[Re](=O)=O |
CH3O3Re- | |
MFCD00192332 | |
methyltrioxorhenium vii, methyltrioxorhenium, methylrhenium trioxide, unii-883d8rdd5q, methylrhenium vii trioxide, mto, methyltrioxorhenium mi, t-4-methyltrioxorhenium, methylrhenium trioxide vii | |
carbanide;trioxorhenium |
Specifications
110°C to 115°C | |
CH3O3Re- | |
MFCD00192332 | |
3927932 | |
Soluble in water. | |
[CH3-].O=[Re](=O)=O | |
249.239 | |
249.24 | |
Light and moisture sensitive |
70197-13-6 | |
CH3ReO3 | |
UN1479 | |
methyltrioxorhenium vii, methyltrioxorhenium, methylrhenium trioxide, unii-883d8rdd5q, methylrhenium vii trioxide, mto, methyltrioxorhenium mi, t-4-methyltrioxorhenium, methylrhenium trioxide vii | |
VZSXFJPZOCRDPW-UHFFFAOYSA-N | |
carbanide;trioxorhenium | |
2734010 | |
98% | |
Methyltrioxorhenium(VII) |
Safety and Handling
GHS H Statement
H272
May intensify fire; oxidizer.
P210-P220-P221-P280-P370+P378q-P501c
H272
missing translation for 'dotInformation' : Transport Hazard Class: 5.1; Packing Group: II; Proper Shipping Name: OXIDIZING SOLID, N.O.S.
missing translation for 'tsca' : No
Recommended Storage : Keep cold; Store under Nitrogen
RUO – Research Use Only
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