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Methyl hydrogen malonate, 96%, Thermo Scientific Chemicals

54.97 € - 558.78 €

Chemical Identifiers

CAS 16695-14-0
Molecular Formula C4H6O4
Molecular Weight (g/mol) 118.088
MDL Number MFCD00667796
InChI Key PBVZQAXFSQKDKK-UHFFFAOYSA-N
Synonym methyl hydrogen malonate, malonic acid monomethyl ester, 3-methoxy-3-oxo-propanoic acid, 1-methyl malonate, hydrogen methyl malonate
PubChem CID 538366
IUPAC Name 3-methoxy-3-oxopropanoic acid
SMILES COC(=O)CC(=O)O
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Products 3
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Product Code Brand Quantity Price Quantity & Availability  
11302949
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Thermo Scientific Alfa Aesar
H27772.06
5 g
54.97 €
5g
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11312949
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Thermo Scientific Alfa Aesar
H27772.14
25 g
170.85 €
25g
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11322949
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Thermo Scientific Alfa Aesar
H27772.22
100 g
558.78 €
100g
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Description

Description

Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Specifications

Chemical Identifiers

16695-14-0
118.088
PBVZQAXFSQKDKK-UHFFFAOYSA-N
538366
COC(=O)CC(=O)O
C4H6O4
MFCD00667796
methyl hydrogen malonate, malonic acid monomethyl ester, 3-methoxy-3-oxo-propanoic acid, 1-methyl malonate, hydrogen methyl malonate
3-methoxy-3-oxopropanoic acid

Specifications

16695-14-0
C4H6O4
MFCD00667796
PBVZQAXFSQKDKK-UHFFFAOYSA-N
3-methoxy-3-oxopropanoic acid
538366
96%
1.128
1.4295
methyl hydrogen malonate, malonic acid monomethyl ester, 3-methoxy-3-oxo-propanoic acid, 1-methyl malonate, hydrogen methyl malonate
COC(=O)CC(=O)O
118.088
118.09
Methyl hydrogen malonate
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

missing translation for 'tsca' : No

Recommended Storage : Keep cold

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only

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