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Diphenylphosphoryl azide, 98%, Thermo Scientific Chemicals

85.32 € - 838.17 €

Chemical Identifiers

CAS 26386-88-9
Molecular Formula C12H10N3O3P
Molecular Weight (g/mol) 275.20
MDL Number MFCD00001987
InChI Key SORGEQQSQGNZFI-UHFFFAOYSA-N
Synonym diphenylphosphoryl azide, diphenyl azidophosphate, diphenylphosphonic azide, diphenyl phosphoryl azide, diphenyl phosphorazidate, phosphorazidic acid, diphenyl ester, azido phenoxy phosphoryl oxy benzene, dppa polymer-bound, diphenylphosphorazidate, unii-gxm91165av
PubChem CID 123414
IUPAC Name [azido(phenoxy)phosphoryl]oxybenzene
SMILES [N-]=[N+]=NP(=O)(OC1=CC=CC=C1)OC1=CC=CC=C1
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Thermo Scientific Acros
409040250
25 g Glass bottle
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25g
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Description

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

C-X bond formation reagent, For Azidation/Diazo transfer
Specifications

Chemical Identifiers

26386-88-9
275.20
SORGEQQSQGNZFI-UHFFFAOYSA-N
123414
[N-]=[N+]=NP(=O)(OC1=CC=CC=C1)OC1=CC=CC=C1
C12H10N3O3P
MFCD00001987
diphenylphosphoryl azide, diphenyl azidophosphate, diphenylphosphonic azide, diphenyl phosphoryl azide, diphenyl phosphorazidate, phosphorazidic acid, diphenyl ester, azido phenoxy phosphoryl oxy benzene, dppa polymer-bound, diphenylphosphorazidate, unii-gxm91165av
[azido(phenoxy)phosphoryl]oxybenzene

Specifications

26386-88-9
1.2730g/mL
112°C
97.5% min. (GC)
1.5500 to 1.5520
04,210; 05,280; 07,138; 08,211; 10,173
1.273
Solubility in water: insoluble. Other solubilities: soluble in most common organic solvents
[N-]=[N+]=NP(=O)(OC1=CC=CC=C1)OC1=CC=CC=C1
275.20
275.19
Liquid
Yellow to Amber
157.0°C (0.2 mmHg)
Authentic
C12H10N3O3P
MFCD00001987
15,3366
diphenylphosphoryl azide, diphenyl azidophosphate, diphenylphosphonic azide, diphenyl phosphoryl azide, diphenyl phosphorazidate, phosphorazidic acid, diphenyl ester, azido phenoxy phosphoryl oxy benzene, dppa polymer-bound, diphenylphosphorazidate, unii-gxm91165av
SORGEQQSQGNZFI-UHFFFAOYSA-N
[azido(phenoxy)phosphoryl]oxybenzene
123414
98%
Diphenylphosphoryl azide
Videos
Safety and Handling

Safety and Handling

GHS H Statement
Toxic if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
Immediately call a POISON CENTER or doctor/physician.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation occur

GHS Signal Word: Danger

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Product Identifier
  • Diphenylphosphoryl azide

Signal Word
  • Danger

Hazard Category
  • Acute toxicity Category 3
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3

Hazard Statement
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H311-Toxic in contact with skin.
  • H331-Toxic if inhaled.
  • H335-May cause respiratory irritation.
  • H301-Toxic if swallowed.

Precautionary Statement
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
  • P302+P352-IF ON SKIN: Wash with plenty of water/.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P312-Call a POISON CENTER/doctor/if you feel unwell.

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only

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