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Diiodomethane, 99%, stab., Thermo Scientific Chemicals
31.36 € - 503.51 €
Chemical Identifiers
CAS | 75-11-6 |
---|---|
Molecular Formula | CH2I2 |
Molecular Weight (g/mol) | 267.84 |
MDL Number | MFCD00001079 |
InChI Key | NZZFYRREKKOMAT-UHFFFAOYSA-N |
Synonym | methylene iodide, methane, diiodo, methylene diiodide, mi-gee, dijodmethan, methylenjodid, dijodmethan czech, methylenjodid czech, di-iodomethane, diiodo-methane |
PubChem CID | 6346 |
IUPAC Name | diiodomethane |
SMILES | ICI |
Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
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Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
11458790
|
Thermo Scientific Alfa Aesar
A15457.14 |
25 g |
31.36 €
25g |
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11432817
|
Thermo Scientific Alfa Aesar
A15457.18 |
50 g |
45.73 €
50g |
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11468790
|
Thermo Scientific Alfa Aesar
A15457.22 |
100 g |
77.89 €
100g |
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11442817
|
Thermo Scientific Alfa Aesar
A15457.30 |
250 g |
154.77 €
250g |
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11478790
|
Thermo Scientific Alfa Aesar
A15457.36 |
500 g |
264.32 €
500g |
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11422817
|
Thermo Scientific Alfa Aesar
A15457.0B |
1000 g |
503.51 €
1000g |
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Description
Diiodomethane is used to determine the density of minerals and other solid samples due to its high density. It is used as an optical contact liquid to determine the refractive index of certain gemstones. In simmons-smith reaction, it acts as a reagent to generate methylene (carbine) free radical. It reacts with olefins to prepare cyclopropanes with high stereo specificity.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsDiiodomethane is used to determine the density of minerals and other solid samples due to its high density. It is used as an optical contact liquid to determine the refractive index of certain gemstones. In simmons-smith reaction, it acts as a reagent to generate methylene (carbine) free radical. It reacts with olefins to prepare cyclopropanes with high stereo specificity.
Solubility
Miscible with alcohol and ether. Slightly miscible with water.
Notes
Light sensitive. Keep container tightly closed in a dry and well-ventilated place. Incompatible with alkali metal salts, strong oxidizing agents, strong bases, metals, lithium, potassium, sodium, sodium oxides and alloys.
Chemical Identifiers
75-11-6 | |
267.84 | |
NZZFYRREKKOMAT-UHFFFAOYSA-N | |
6346 | |
ICI |
CH2I2 | |
MFCD00001079 | |
methylene iodide, methane, diiodo, methylene diiodide, mi-gee, dijodmethan, methylenjodid, dijodmethan czech, methylenjodid czech, di-iodomethane, diiodo-methane | |
diiodomethane |
Specifications
75-11-6 | |
3.322 | |
None | |
CH2I2 | |
MFCD00001079 | |
1696892 | |
14,6066 | |
Miscible with alcohol and ether. Slightly miscible with water. | |
ICI | |
267.84 | |
267.84 | |
Liquid |
5°C to 6°C | |
180°C to 181°C (decomposition) | |
99%, stab. | |
1.74 | |
UN2810 | |
Light sensitive | |
methylene iodide, methane, diiodo, methylene diiodide, mi-gee, dijodmethan, methylenjodid, dijodmethan czech, methylenjodid czech, di-iodomethane, diiodo-methane | |
NZZFYRREKKOMAT-UHFFFAOYSA-N | |
diiodomethane | |
6346 | |
99% | |
Diiodomethane, stabilized |
Safety and Handling
GHS H Statement
H302-H332-H315-H319-H335
Harmful if swallowed.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P362-P501c
H301-H315-H318-H335
missing translation for 'dotInformation' : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: TOXIC, LIQUIDS, ORGANIC, N.O.S.
missing translation for 'einecsNumber' : 200-841-5
missing translation for 'rtecsNumber' : PA8575000
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures
- Diiodomethane, stabilized
Signal Word
- Danger
Hazard Category
- Acute toxicity Category 4
- Serious eye damage/eye irritation Category 1
- Skin corrosion/irritation Category 2
- Specific target organ toxicity Category 3
Hazard Statement
- H302-Harmful if swallowed.
- H315-Causes skin irritation.
- H318-Causes serious eye damage.
- H335-May cause respiratory irritation.
Precautionary Statement
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P302+P352-IF ON SKIN: Wash with plenty of water/soap.
- P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P310-Immediately call a POISON CENTER/doctor/.
Supplemental information
- MIXTURE LIST-Contains : Methylene iodide
RUO – Research Use Only