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Diiodomethane, 99%, stab., Thermo Scientific Chemicals

31.36 € - 503.51 €

Chemical Identifiers

CAS 75-11-6
Molecular Formula CH2I2
Molecular Weight (g/mol) 267.84
MDL Number MFCD00001079
InChI Key NZZFYRREKKOMAT-UHFFFAOYSA-N
Synonym methylene iodide, methane, diiodo, methylene diiodide, mi-gee, dijodmethan, methylenjodid, dijodmethan czech, methylenjodid czech, di-iodomethane, diiodo-methane
PubChem CID 6346
IUPAC Name diiodomethane
SMILES ICI
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Products 6
Product Code Brand Quantity Price Quantity & Availability  
Product Code Brand Quantity Price Quantity & Availability  
11458790
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Thermo Scientific Alfa Aesar
A15457.14
25 g
31.36 €
25g
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11432817
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Thermo Scientific Alfa Aesar
A15457.18
50 g
45.73 €
50g
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11468790
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Thermo Scientific Alfa Aesar
A15457.22
100 g
77.89 €
100g
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11442817
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Thermo Scientific Alfa Aesar
A15457.30
250 g
154.77 €
250g
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11478790
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Thermo Scientific Alfa Aesar
A15457.36
500 g
264.32 €
500g
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11422817
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Thermo Scientific Alfa Aesar
A15457.0B
1000 g
503.51 €
1000g
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Description

Description

Diiodomethane is used to determine the density of minerals and other solid samples due to its high density. It is used as an optical contact liquid to determine the refractive index of certain gemstones. In simmons-smith reaction, it acts as a reagent to generate methylene (carbine) free radical. It reacts with olefins to prepare cyclopropanes with high stereo specificity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diiodomethane is used to determine the density of minerals and other solid samples due to its high density. It is used as an optical contact liquid to determine the refractive index of certain gemstones. In simmons-smith reaction, it acts as a reagent to generate methylene (carbine) free radical. It reacts with olefins to prepare cyclopropanes with high stereo specificity.

Solubility
Miscible with alcohol and ether. Slightly miscible with water.

Notes
Light sensitive. Keep container tightly closed in a dry and well-ventilated place. Incompatible with alkali metal salts, strong oxidizing agents, strong bases, metals, lithium, potassium, sodium, sodium oxides and alloys.
Specifications

Chemical Identifiers

75-11-6
267.84
NZZFYRREKKOMAT-UHFFFAOYSA-N
6346
ICI
CH2I2
MFCD00001079
methylene iodide, methane, diiodo, methylene diiodide, mi-gee, dijodmethan, methylenjodid, dijodmethan czech, methylenjodid czech, di-iodomethane, diiodo-methane
diiodomethane

Specifications

75-11-6
3.322
None
CH2I2
MFCD00001079
1696892
14,6066
Miscible with alcohol and ether. Slightly miscible with water.
ICI
267.84
267.84
Liquid
5°C to 6°C
180°C to 181°C (decomposition)
99%, stab.
1.74
UN2810
Light sensitive
methylene iodide, methane, diiodo, methylene diiodide, mi-gee, dijodmethan, methylenjodid, dijodmethan czech, methylenjodid czech, di-iodomethane, diiodo-methane
NZZFYRREKKOMAT-UHFFFAOYSA-N
diiodomethane
6346
99%
Diiodomethane, stabilized
Videos
Safety and Handling

Safety and Handling

GHS H Statement
H302-H332-H315-H319-H335
Harmful if swallowed.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P362-P501c

H301-H315-H318-H335

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missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

Product Identifier
  • Diiodomethane, stabilized

Signal Word
  • Danger

Hazard Category
  • Acute toxicity Category 4
  • Serious eye damage/eye irritation Category 1
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3

Hazard Statement
  • H302-Harmful if swallowed.
  • H315-Causes skin irritation.
  • H318-Causes serious eye damage.
  • H335-May cause respiratory irritation.

Precautionary Statement
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.

Supplemental information
  • MIXTURE LIST-Contains : Methylene iodide

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only