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Chloro(1,5-cyclooctadiene)rhodium(I) dimer, Thermo Scientific Chemicals

214.07 € - 531.65 €

Chemical Identifiers

CAS 12092-47-6
Molecular Formula C16H24Cl2Rh2
Molecular Weight (g/mol) 493.08
MDL Number MFCD00012415
InChI Key QSUDXYGZLAJAQU-MIXQCLKLSA-L
Synonym chloro 1,5-cyclooctadiene rhodium i dimer, 1z,5z-cycloocta-1,5-diene; rhodium; dichloride, bis 1,5-cyclooctadiene dirhodium i dichloride, 1,5-cyclooctadiene rhodium chloride dimer, ccris 5036, di-?-chlorobis 1,2,5,6-?-1,5-cyclooctadiene diiridium, rhodium-1,5-cyclooctadiene chloride, 1,5-cyclooctadiene-iridium i chloride dimer, chloro 1,5-cyclooctadiene iridium i dimer
PubChem CID 6436379
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride
SMILES [Cl-].[Cl-].[Rh+].[Rh+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1
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Products 2
Product Code Brand Quantity Price Quantity & Availability  
Product Code Brand Quantity Price Quantity & Availability  
11375968
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Thermo Scientific Alfa Aesar
010466.MD
250 mg
214.07 €
250mg
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11365968
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Thermo Scientific Alfa Aesar
010466.03
1 g
531.65 €
1g
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Description

Description

It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

12092-47-6
493.08
QSUDXYGZLAJAQU-MIXQCLKLSA-L
6436379
[Cl-].[Cl-].[Rh+].[Rh+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1
C16H24Cl2Rh2
MFCD00012415
chloro 1,5-cyclooctadiene rhodium i dimer, 1z,5z-cycloocta-1,5-diene; rhodium; dichloride, bis 1,5-cyclooctadiene dirhodium i dichloride, 1,5-cyclooctadiene rhodium chloride dimer, ccris 5036, di-?-chlorobis 1,2,5,6-?-1,5-cyclooctadiene diiridium, rhodium-1,5-cyclooctadiene chloride, 1,5-cyclooctadiene-iridium i chloride dimer, chloro 1,5-cyclooctadiene iridium i dimer
(1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride

Specifications

12092-47-6
Yellow to Orange
C16H24Cl2Rh2
Air sensitive; Hygroscopic
Soluble in chloroform,dichloromethane,and methanol; Sparingly soluble in most common solvents.
[Cl-].[Cl-].[Rh+].[Rh+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1
493.08
493.08
Chloro(1,5-cyclooctadiene)rhodium(I) dimer
243°C (decomposition)
Odorless
MFCD00012415
chloro 1,5-cyclooctadiene rhodium i dimer, 1z,5z-cycloocta-1,5-diene; rhodium; dichloride, bis 1,5-cyclooctadiene dirhodium i dichloride, 1,5-cyclooctadiene rhodium chloride dimer, ccris 5036, di-?-chlorobis 1,2,5,6-?-1,5-cyclooctadiene diiridium, rhodium-1,5-cyclooctadiene chloride, 1,5-cyclooctadiene-iridium i chloride dimer, chloro 1,5-cyclooctadiene iridium i dimer
QSUDXYGZLAJAQU-MIXQCLKLSA-L
(1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride
6436379
Crystalline
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Safety and Handling

Safety and Handling

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missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

SDS
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RUO – Research Use Only