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Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%, Thermo Scientific Chemicals
115.58 € - 2140.65 €
Chemical Identifiers
| CAS | 12112-67-3 |
|---|---|
| Molecular Formula | C16H24Cl2Ir2 |
| Molecular Weight (g/mol) | 671.70 |
| MDL Number | MFCD00012414 |
| InChI Key | ZFOUDQNHNLDNLD-MIXQCLKLSA-L |
| Synonym | chloro 1,5-cyclooctadiene iridium i dimer, bis 1,5-cyclooctadiene diiridium i dichloride, 1z,5z-cycloocta-1,5-diene; iridium; dichloride, iridium, di-.mu.-chlorobis 1,2,5,6-.eta.-1,5-cyclooctadiene di, ir2cl2 cod 2, chloro-1,5-cyclooctadiene iridium i dimer, 1z,5z-cycloocta-1,5-diene; iridium 1+ |
| PubChem CID | 6436381 |
| IUPAC Name | (1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride |
| SMILES | [Cl-].[Cl-].[Ir+].[Ir+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1 |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
11327537
|
Thermo Scientific Alfa Aesar
012749.01 |
0.25 g |
115.58 €
0.25g |
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|
11307537
|
Thermo Scientific Alfa Aesar
012749.03 |
1 g |
467.33 €
1g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
|
11317537
|
Thermo Scientific Alfa Aesar
012749.06 |
5 g |
2140.65 €
5g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Description
Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 12112-67-3 | |
| 671.70 | |
| ZFOUDQNHNLDNLD-MIXQCLKLSA-L | |
| 6436381 | |
| [Cl-].[Cl-].[Ir+].[Ir+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1 |
| C16H24Cl2Ir2 | |
| MFCD00012414 | |
| chloro 1,5-cyclooctadiene iridium i dimer, bis 1,5-cyclooctadiene diiridium i dichloride, 1z,5z-cycloocta-1,5-diene; iridium; dichloride, iridium, di-.mu.-chlorobis 1,2,5,6-.eta.-1,5-cyclooctadiene di, ir2cl2 cod 2, chloro-1,5-cyclooctadiene iridium i dimer, 1z,5z-cycloocta-1,5-diene; iridium 1+ | |
| (1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride |
Specifications
| 12112-67-3 | |
| White | |
| C16H24Cl2Ir2 | |
| chloro 1,5-cyclooctadiene iridium i dimer, bis 1,5-cyclooctadiene diiridium i dichloride, 1z,5z-cycloocta-1,5-diene; iridium; dichloride, iridium, di-.mu.-chlorobis 1,2,5,6-.eta.-1,5-cyclooctadiene di, ir2cl2 cod 2, chloro-1,5-cyclooctadiene iridium i dimer, 1z,5z-cycloocta-1,5-diene; iridium 1+ | |
| ZFOUDQNHNLDNLD-MIXQCLKLSA-L | |
| (1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride | |
| 6436381 | |
| Crystalline Powder |
| 190°C (decomposition) | |
| Odorless | |
| MFCD00012414 | |
| Soluble in chloroform and toluene. Slightly soluble in acetone and alcohol. Insoluble in water. | |
| [Cl-].[Cl-].[Ir+].[Ir+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1 | |
| 671.70 | |
| 671.71 | |
| Chloro(1, 5-cyclooctadiene)iridium(I) dimer |
Safety and Handling
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
missing translation for 'einecsNumber' : 235-170-7
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures
Product Identifier
Signal Word
Hazard Category
Hazard Statement
Precautionary Statement
Supplemental information
- Chloro(1,5-cyclooctadiene)iridium(I) dimer
Signal Word
- Warning
Hazard Category
- Serious eye damage/eye irritation Category 2
- Skin corrosion/irritation Category 2
- Specific target organ toxicity Category 3
Hazard Statement
- H315-Causes skin irritation.
- H319-Causes serious eye irritation.
- H335-May cause respiratory irritation.
Precautionary Statement
- P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P302+P352-IF ON SKIN: Wash with plenty of water/soap.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental information
- MIXTURE LIST-Contains : Chloro(1,5-cyclooctadiene)iridium(I) dimer
RUO – Research Use Only