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Bismuth(III) chloride, 97+% (dry wt.), may cont. up to 3% water, Thermo Scientific Chemicals
45.43 € - 529.64 €
Chemical Identifiers
CAS | 7787-60-2 |
---|---|
Molecular Formula | BiCl3 |
Molecular Weight (g/mol) | 315.33 |
MDL Number | MFCD00003461 |
InChI Key | JHXKRIRFYBPWGE-UHFFFAOYSA-K |
Synonym | bismuth trichloride, bismuth chloride, trichlorobismuthine, trichlorobismuth, bismuth iii chloride, bismuthine, trichloro, trichlorobismute, bismuth lll chloride |
PubChem CID | 24591 |
IUPAC Name | trichlorobismuthane |
SMILES | Cl[Bi](Cl)Cl |
Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
---|---|---|---|---|---|---|---|---|---|
Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
11458763
|
Thermo Scientific Alfa Aesar
A10510.14 |
25 g |
45.43 €
25g |
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11468763
|
Thermo Scientific Alfa Aesar
A10510.22 |
100 g |
136.68 €
100g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
11478763
|
Thermo Scientific Alfa Aesar
A10510.36 |
500 g |
529.64 €
500g |
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Description
Bismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsBismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.
Solubility
Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.
Notes
Hygroscopic. Incompatible with strong oxidizing agents.
Chemical Identifiers
7787-60-2 | |
315.33 | |
JHXKRIRFYBPWGE-UHFFFAOYSA-K | |
24591 | |
Cl[Bi](Cl)Cl |
BiCl3 | |
MFCD00003461 | |
bismuth trichloride, bismuth chloride, trichlorobismuthine, trichlorobismuth, bismuth iii chloride, bismuthine, trichloro, trichlorobismute, bismuth lll chloride | |
trichlorobismuthane |
Specifications
∼430°C (sublimation) | |
7787-60-2 | |
MFCD00003461 | |
14,1262 | |
Soluble in hydrochloric acid,nitric acid,diethyl ether,ethyl acetate and acetone. Insoluble in alcohol. | |
Cl[Bi](Cl)Cl | |
315.33 | |
315.34 | |
May contain up to 3% water | |
Moisture sensitive | |
(dry wt.) |
230°C to 232°C | |
BiCl3 | |
UN3260 | |
bismuth trichloride, bismuth chloride, trichlorobismuthine, trichlorobismuth, bismuth iii chloride, bismuthine, trichloro, trichlorobismute, bismuth lll chloride | |
JHXKRIRFYBPWGE-UHFFFAOYSA-K | |
trichlorobismuthane | |
24591 | |
98% | |
Irritating | |
4.75 | |
Bismuth (III) chloride |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
missing translation for 'einecsNumber' : 232-123-2
missing translation for 'rtecsNumber' : EB2690000
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures
- Bismuth(III) chloride
Signal Word
- Danger
Hazard Category
- Skin corrosion/irritation Category 1 B
Hazard Statement
- H314-Causes severe skin burns and eye damage.
Precautionary Statement
- P260-Do not breathe dust/fume/gas/mist/vapours/spray.
- P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P405-Store locked up.
- P501-Dispose of contents/container to .
RUO – Research Use Only
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