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Allyltrimethylsilane, 98+%, Thermo Scientific Chemicals
53.70 € - 686.00 €
Chemical Identifiers
| CAS | 762-72-1 |
|---|---|
| Molecular Formula | C6H14Si |
| Molecular Weight (g/mol) | 114.263 |
| MDL Number | MFCD00008635 |
| InChI Key | HYWCXWRMUZYRPH-UHFFFAOYSA-N |
| Synonym | allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane |
| PubChem CID | 69808 |
| IUPAC Name | trimethyl(prop-2-enyl)silane |
| SMILES | C[Si](C)(C)CC=C |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
11497626
|
Thermo Scientific Alfa Aesar
A14662.09 |
10 g |
53.70 €
10g |
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|
11407636
|
Thermo Scientific Alfa Aesar
A14662.18 |
50 g |
201.00 €
50g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
|
11364609
|
Thermo Scientific Alfa Aesar
A14662.30 |
250 g |
686.00 €
250g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Description
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsAllyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.
Solubility
Miscible with organic solvents. Immiscible with water.
Notes
Store in cool place. Incompatible with strong oxidizing agents and acids.
Chemical Identifiers
| 762-72-1 | |
| 114.263 | |
| HYWCXWRMUZYRPH-UHFFFAOYSA-N | |
| 69808 | |
| C[Si](C)(C)CC=C |
| C6H14Si | |
| MFCD00008635 | |
| allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane | |
| trimethyl(prop-2-enyl)silane |
Specifications
| 85°C to 86°C | |
| C6H14Si | |
| UN1993 | |
| −10°C (14°F) | |
| Miscible with organic solvents. Immiscible with water. | |
| C[Si](C)(C)CC=C | |
| 114.263 | |
| 114.27 | |
| 1.408 | |
| Allyltrimethylsilane |
| 762-72-1 | |
| MFCD00008635 | |
| 906755 | |
| allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane | |
| HYWCXWRMUZYRPH-UHFFFAOYSA-N | |
| trimethyl(prop-2-enyl)silane | |
| 69808 | |
| ≥98% | |
| 0.717 |
Safety and Handling
GHS H Statement
H225-H315-H319-H335
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
H225-H315-H319-H335
missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
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missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures
Hazard Category
Hazard Statement
Precautionary Statement
- LONG-TERM AQUATIC HAZARD Chronic 2
Hazard Statement
- H411-Toxic to aquatic life with long lasting effects.
Precautionary Statement
- P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
- P403+P233-Store in a well-ventilated place. Keep container tightly closed.
RUO – Research Use Only