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  7. Allyltrimethylsilane, 98+%, Thermo Scientific Chemicals

Allyltrimethylsilane, 98+%, Thermo Scientific Chemicals

Product Code. 11497626
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Quantity:
10 g
50 g
250 g
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Description

Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.

Solubility
Miscible with organic solvents. Immiscible with water.

Notes
Store in cool place. Incompatible with strong oxidizing agents and acids.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 762-72-1
Molecular Formula C6H14Si
Molecular Weight (g/mol) 114.263
MDL Number MFCD00008635
InChI Key HYWCXWRMUZYRPH-UHFFFAOYSA-N
Synonym allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane
PubChem CID 69808
IUPAC Name trimethyl(prop-2-enyl)silane
SMILES C[Si](C)(C)CC=C

Specifications

Boiling Point 85°C to 86°C
Quantity 10 g
UN Number UN1993
Beilstein 906755
Flash Point −10°C (14°F)
Solubility Information Miscible with organic solvents. Immiscible with water.
Formula Weight 114.27
Percent Purity ≥98%
Refractive Index 1.408
Density 0.717
Chemical Name or Material Allyltrimethylsilane
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Safety and Handling

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Hazard Category
  • LONG-TERM AQUATIC HAZARD Chronic 2
 Hazard Statement
  • H411-Toxic to aquatic life with long lasting effects.
 Precautionary Statement
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P403+P233-Store in a well-ventilated place. Keep container tightly closed.

RUO – Research Use Only

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