missing translation for 'onlineSavingsMsg'
Learn More
  1. Home
  2. Products
  3. Chemicals
  4. Organic compounds
  5. Organic metal halides
  6. Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals
  • missing translation for 'structureSearchLink'
  • Print

Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals

Product Code. 11346707
missing translation for 'orderingAttributeHoverText'
Quantity:
0.25 g
1 g
5 g
This item is not returnable. View return policy
This item is not returnable. View return policy

Description

Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 12012-95-2
Molecular Formula C6H10Cl2Pd2
Molecular Weight (g/mol) 365.89
MDL Number MFCD00044874
InChI Key PENAXHPKEVTBLF-UHFFFAOYSA-L
Synonym allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium
PubChem CID 61538
IUPAC Name chloropalladium(1+);prop-1-ene
SMILES Cl[Pd].Cl[Pd].c:c:c.c:c:c

Specifications

Melting Point 120°C (decomposition)
Color Yellow
Quantity 1 g
Beilstein 4124623
Sensitivity Air and moisture sensitive
Solubility Information Very soluble in dichloromethane and dichloroethane; Slightly soluble in toluene,insoluble in waterSoluble in chloroform,benzene,acetone and dichloromethane,dichloroethane and methanol; Slightly soluble in toluene; Insoluble in water.
Formula Weight 365.85
Concentration or Composition (by Analyte or Components) Pd 56.0% min.
Physical Form Powder
Chemical Name or Material Allylpalladium(II) chloride dimer

RUO – Research Use Only

Product Content Correction

Your input is important to us. Please complete this form to provide feedback related to the content on this product.

Product Title

By clicking Submit, you acknowledge that you may be contacted by Fisher Scientific in regards to the feedback you have provided in this form. We will not share your information for any other purposes. All contact information provided shall also be maintained in accordance with our Privacy Policy.

Thank You! Your feedback has been submitted. Fisher Scientific is always working to improve our content for you. We appreciate your feedback.