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3-Bromo-1-trimethylsilyl-1-propyne, 98%, Thermo Scientific Chemicals
108.00 € - 385.00 €
Chemical Identifiers
| CAS | 38002-45-8 |
|---|---|
| Molecular Formula | C6H11BrSi |
| Molecular Weight (g/mol) | 191.143 |
| MDL Number | MFCD00134460 |
| InChI Key | GAPRPFRDVCCCHR-UHFFFAOYSA-N |
| Synonym | 3-bromo-1-trimethylsilyl-1-propyne, 3-bromoprop-1-yn-1-yl trimethylsilane, 3-bromo-1-propynyl trimethylsilane, 3-trimethylsilyl propargyl bromide, 3-bromoprop-1-ynyl trimethyl silane, silane, 3-bromo-1-propynyl trimethyl, 3-bromoprop-1-yn-1-yl trimethyl silane, acmc-1cthe, ksc496i3r |
| PubChem CID | 642589 |
| IUPAC Name | 3-bromoprop-1-ynyl(trimethyl)silane |
| SMILES | C[Si](C)(C)C#CCBr |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
15430278
|
Thermo Scientific Alfa Aesar
H53451.06 |
5 g |
108.00 €
5g |
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|
15440278
|
Thermo Scientific Alfa Aesar
H53451.14 |
25 g |
385.00 €
25g |
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Description
3-Bromo-1-trimethylsilyl-1-propyne is used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It acts as a propargylating agent and used for the alkylation of dianion of beta-keto esters at gamma-carbon. It plays an important role in the synthesis of allenic alcohols and terminal conjugated enynes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications3-Bromo-1-trimethylsilyl-1-propyne is used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It acts as a propargylating agent and used for the alkylation of dianion of beta-keto esters at gamma-carbon. It plays an important role in the synthesis of allenic alcohols and terminal conjugated enynes.
Solubility
Immiscible with water.
Notes
Store in cool place. Incompatible with strong oxidizing agents.
Chemical Identifiers
| 38002-45-8 | |
| 191.143 | |
| GAPRPFRDVCCCHR-UHFFFAOYSA-N | |
| 642589 | |
| C[Si](C)(C)C#CCBr |
| C6H11BrSi | |
| MFCD00134460 | |
| 3-bromo-1-trimethylsilyl-1-propyne, 3-bromoprop-1-yn-1-yl trimethylsilane, 3-bromo-1-propynyl trimethylsilane, 3-trimethylsilyl propargyl bromide, 3-bromoprop-1-ynyl trimethyl silane, silane, 3-bromo-1-propynyl trimethyl, 3-bromoprop-1-yn-1-yl trimethyl silane, acmc-1cthe, ksc496i3r | |
| 3-bromoprop-1-ynyl(trimethyl)silane |
Specifications
| 44°C to 45°C (2mmHg) | |
| C6H11BrSi | |
| MFCD00134460 | |
| 63°C (145°F) | |
| Immiscible with water. | |
| C[Si](C)(C)C#CCBr | |
| 191.143 | |
| 191.14 | |
| 1.483 | |
| 3-Bromo-1-trimethylsilyl-1-propyne |
| 38002-45-8 | |
| BrCH2C≡CSi(CH3)3 | |
| 2037650 | |
| 3-bromo-1-trimethylsilyl-1-propyne, 3-bromoprop-1-yn-1-yl trimethylsilane, 3-bromo-1-propynyl trimethylsilane, 3-trimethylsilyl propargyl bromide, 3-bromoprop-1-ynyl trimethyl silane, silane, 3-bromo-1-propynyl trimethyl, 3-bromoprop-1-yn-1-yl trimethyl silane, acmc-1cthe, ksc496i3r | |
| GAPRPFRDVCCCHR-UHFFFAOYSA-N | |
| 3-bromoprop-1-ynyl(trimethyl)silane | |
| 642589 | |
| 98% | |
| 1.17 |
Safety and Handling
GHS H Statement
H315-H319-H335-H227
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.
P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
H227-H315-H319-H335
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only