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2,2,6,6-Tetramethylpiperidine, 98+%, Thermo Scientific Chemicals

38.19 € - 413.06 €

Chemical Identifiers

CAS 768-66-1
Molecular Formula C9H19N
Molecular Weight (g/mol) 141.258
MDL Number MFCD00005985
InChI Key RKMGAJGJIURJSJ-UHFFFAOYSA-N
Synonym norpempidine, piperidine, 2,2,6,6-tetramethyl, 2,2,6,6-tetramethyl piperidine, unii-44n9s1ycfm, 2,2,6,6-tetramethylpeperidine, 44n9s1ycfm, 2,2,6,6 tetramethyl piperidine, 2,2,6,6-tetramethyl-piperidine, pubchem7259, acmc-209p6i
PubChem CID 13035
IUPAC Name 2,2,6,6-tetramethylpiperidine
SMILES CC1(CCCC(N1)(C)C)C
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Thermo Scientific Alfa Aesar
A18712.06
5 g
38.19 €
5g
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Thermo Scientific Alfa Aesar
A18712.14
25 g
120.60 €
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Thermo Scientific Alfa Aesar
A18712.22
100 g
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Description

Description

2,2,6,6-Tetramethylpiperidine is a hindered base used to prepare metallo-amide bases and selective generation of silylketene acetals. It is used in the preparation of hibarimicinone, (Z)-silylketene acetal and 4-substituted quinazoline. It acts as a precursor to Lithium tetramethylpiperidide and (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl radical.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2,2,6,6-Tetramethylpiperidine is a hindered base used to prepare metallo-amide bases and selective generation of silylketene acetals. It is used in the preparation of hibarimicinone, (Z)-silylketene acetal and 4-substituted quinazoline. It acts as a precursor to Lithium tetramethylpiperidide and (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl radical.

Solubility
Miscible with water, ether, ethanol and acetic acid. Slightly miscible with chloroform.

Notes
Incompatible with oxidizing agents, bases, strong acids, acid anhydrides, carbon dioxide and acid chlorides.
Specifications

Chemical Identifiers

768-66-1
141.258
RKMGAJGJIURJSJ-UHFFFAOYSA-N
13035
CC1(CCCC(N1)(C)C)C
C9H19N
MFCD00005985
norpempidine, piperidine, 2,2,6,6-tetramethyl, 2,2,6,6-tetramethyl piperidine, unii-44n9s1ycfm, 2,2,6,6-tetramethylpeperidine, 44n9s1ycfm, 2,2,6,6 tetramethyl piperidine, 2,2,6,6-tetramethyl-piperidine, pubchem7259, acmc-209p6i
2,2,6,6-tetramethylpiperidine

Specifications

768-66-1
0.832
34°C (93°F)
C9H19N
MFCD00005985
103296
norpempidine, piperidine, 2,2,6,6-tetramethyl, 2,2,6,6-tetramethyl piperidine, unii-44n9s1ycfm, 2,2,6,6-tetramethylpeperidine, 44n9s1ycfm, 2,2,6,6 tetramethyl piperidine, 2,2,6,6-tetramethyl-piperidine, pubchem7259, acmc-209p6i
RKMGAJGJIURJSJ-UHFFFAOYSA-N
2,2,6,6-tetramethylpiperidine
13035
≥98%
-59°C
152°C to 154°C
Amine-like
1.444
UN2733
Air Sensitive
Miscible with water,ether,ethanol and acetic acid. Slightly miscible with chloroform.
CC1(CCCC(N1)(C)C)C
141.258
141.26
2,2,6,6-Tetramethylpiperidine
Videos
Safety and Handling

Safety and Handling

GHS H Statement
H314-H318-H226-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Flammable liquid and vapour.
Harmful if swallowed.

P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P312-P330-P332+P313-P363-P370+P378q-P501c

H226-H301-H315-H319-H335

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missing translation for 'rtecsNumber' : TN4220000

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

Signal Word
  • Danger

Hazard Category
  • Acute toxicity Category 3
  • Acute toxicity Category 4
  • Serious eye damage/eye irritation Category 1
  • Flammable liquid Category 3
  • Skin corrosion/irritation Category 1 C

Hazard Statement
  • H226-Flammable liquid and vapour.
  • H301-Toxic if swallowed.
  • H314-Causes severe skin burns and eye damage.
  • H318-Causes serious eye damage.
  • H332-Harmful if inhaled.

Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only

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