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1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate, Thermo Scientific Chemicals

Hydrogenation

170.00 € - 558.00 €

Chemical Identifiers

CAS 38465-86-0
Molecular Formula C34H38F6IrP3
Molecular Weight (g/mol) 845.81
MDL Number MFCD00064800
InChI Key LXKHQEQLBSJJCO-JXNOXZOESA-N
Synonym 1,5-cyclooctadiene bis methyldiphenylphosphine iridium i hexafluorophosphate, 1,5-cyclooctadiene bis methyldiphenylphosphine ir, 1,5-cyclooctadienebis methyldiphenylphosphine iridium i hexafluorophosphate, 1z,5z-cycloocta-1,5-diene; iridium; methyl diphenyl phosphane; hexafluorophosphate, iridium 1+ 1,5-cyclooctadiene, z,z-bis methyldiphenylphosphane hexafluorophosphate
PubChem CID 5702663
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;iridium;methyl(diphenyl)phosphane;hexafluorophosphate
SMILES [Ir+].F[P-](F)(F)(F)(F)F.C1C\C=C/CC\C=C/1.CP(C1=CC=CC=C1)C1=CC=CC=C1.CP(C1=CC=CC=C1)C1=CC=CC=C1
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Product Code Brand Quantity Price Quantity & Availability  
11383477
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Thermo Scientific Alfa Aesar
018809.02
0.5 g
170.00 €
0.50g
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11373477
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Thermo Scientific Alfa Aesar
018809.04
2 g
558.00 €
2g
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Description

Description

1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for isomerization of allylic ethers of glycerol and glucose to the corresponding 1-propenyl ethers. It is also used as a catalyst in hydrogenation reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

38465-86-0
845.81
LXKHQEQLBSJJCO-JXNOXZOESA-N
5702663
[Ir+].F[P-](F)(F)(F)(F)F.C1C\C=C/CC\C=C/1.CP(C1=CC=CC=C1)C1=CC=CC=C1.CP(C1=CC=CC=C1)C1=CC=CC=C1
C34H38F6IrP3
MFCD00064800
1,5-cyclooctadiene bis methyldiphenylphosphine iridium i hexafluorophosphate, 1,5-cyclooctadiene bis methyldiphenylphosphine ir, 1,5-cyclooctadienebis methyldiphenylphosphine iridium i hexafluorophosphate, 1z,5z-cycloocta-1,5-diene; iridium; methyl diphenyl phosphane; hexafluorophosphate, iridium 1+ 1,5-cyclooctadiene, z,z-bis methyldiphenylphosphane hexafluorophosphate
(1Z,5Z)-cycloocta-1,5-diene;iridium;methyl(diphenyl)phosphane;hexafluorophosphate

Specifications

38465-86-0
C34H38F6IrP3
Air and moisture sensitive
Soluble in acetone; Insoluble in water.
[Ir+].F[P-](F)(F)(F)(F)F.C1C\C=C/CC\C=C/1.CP(C1=CC=CC=C1)C1=CC=CC=C1.CP(C1=CC=CC=C1)C1=CC=CC=C1
845.81
845.79
1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
224°C (decomposition)
MFCD00064800
1,5-cyclooctadiene bis methyldiphenylphosphine iridium i hexafluorophosphate, 1,5-cyclooctadiene bis methyldiphenylphosphine ir, 1,5-cyclooctadienebis methyldiphenylphosphine iridium i hexafluorophosphate, 1z,5z-cycloocta-1,5-diene; iridium; methyl diphenyl phosphane; hexafluorophosphate, iridium 1+ 1,5-cyclooctadiene, z,z-bis methyldiphenylphosphane hexafluorophosphate
LXKHQEQLBSJJCO-JXNOXZOESA-N
(1Z,5Z)-cycloocta-1,5-diene;iridium;methyl(diphenyl)phosphane;hexafluorophosphate
5702663
Crystalline
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Safety and Handling

Safety and Handling

GHS H Statement
H301-H315-H319-H335
Toxic if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

H302+H312+H332-H315-H319-H335

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures; Store under Argon

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only