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1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals
Chemical Identifiers
| CAS | 12150-46-8 |
|---|---|
| Molecular Formula | C34H28FeP2 |
| Molecular Weight (g/mol) | 554.39 |
| MDL Number | MFCD00001422 |
| InChI Key | KZPYGQFFRCFCPP-UHFFFAOYSA-N |
| IUPAC Name | λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide) |
| SMILES | [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1 |
Description
1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.
Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.
Chemical Identifiers
| 12150-46-8 | |
| 554.39 | |
| KZPYGQFFRCFCPP-UHFFFAOYSA-N | |
| [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1 |
| C34H28FeP2 | |
| MFCD00001422 | |
| λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide) |
Specifications
| 12150-46-8 | |
| 0.97 | |
| MFCD00001422 | |
| Soluble in chloroform,dichloromethane,alcohol and pentane. Insoluble in water. | |
| [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1 | |
| 554.39 | |
| 97% |
| ∽182°C (decomposition) | |
| C34H28FeP2 | |
| Air sensitive | |
| KZPYGQFFRCFCPP-UHFFFAOYSA-N | |
| λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide) | |
| 554.4 | |
| 1, 1'-Bis(diphenylphosphino)ferrocene |
Safety and Handling
GHS H Statement
H315-H319-H335
P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P312-P330-P363-P501c
H301-H312-H332
missing translation for 'dotInformation' : Hazard Class: 6.1; Packaging Group: III
missing translation for 'tsca' : No
missing translation for 'storageNote' : Air Sensitive
Recommended Storage : Keep cold; Store under Argon
RUO – Research Use Only